Simulation of spherulite growth using a comprehensive approach to modeling the first-order isotropic/smectic-A mesophase transition

A comprehensive modeling and simulation study of the first-order isotropic/smectic-A transition is presented and applied to phase diagram computation and two-dimensional spherulite growth. An approach based on nonlinear optimization, that incorporates experimental data (from 12CB, dodecyl-cyanobiphenyl), is used to determine physically realistic model parameters. These parameters are then used in conjunction with an optimized phase diagram computation method. Additionally, a time-dependent formulation is presented and applied to the study of two-dimensional smectic-A spherulite growth. These results show the growth kinematics and defect dynamics of nanoscale smectic-A spherulite growth in an isotropic phase with an initially radial layer configuration

Quantum lattice models at intermediate temperatures

We analyze the free energy and construct the Gibbs-KMS states for a class of quantum lattice systems, at low temperatures and when the interactions are almost diagonal in a suitable basis. We study systems with continuous symmetry, but our results are valid for discrete symmetry breaking only. Such phase transitions occur at intermediate temperatures where the continuous symmetry is not broken, while at very low temperature continuous symmetry breaking may occur.Comment: 25 pages, 6 figure

Quantum limited measurements of atomic scattering properties

We propose a method to perform precision measurements of the interaction parameters in systems of N ultra-cold spin 1/2 atoms. The spectroscopy is realized by first creating a coherent spin superposition of the two relevant internal states of each atom and then letting the atoms evolve under a squeezing Hamiltonian. The non-linear nature of the Hamiltonian decreases the fundamental limit imposed by the Heisenberg uncertainty principle to N^(-2), a factor of N smaller than the fundamental limit achievable with non-interacting atoms. We study the effect of decoherence and show that even with decoherence, entangled states can outperform the signal to noise limit of non-entangled states. We present two possible experimental implementations of the method using Bose-Einstein spinor condensates and fermionic atoms loaded in optical lattices and discuss their advantages and disadvantages.Comment: 7 pages, 5 figures. References adde

Wave polarizations for a beam-like gravitational wave in quadratic curvature gravity

We compute analytically the tidal field and polarizations of an exact gravitational wave generated by a cylindrical beam of null matter of finite width and length in quadratic curvature gravity. We propose that this wave can represent the gravitational wave that keep up with the high energy photons produced in a gamma ray burst (GRB) source.Comment: 5 pages, 3 figures, minor corrections, to appear in CQ

Simulating accelerated atoms coupled to a quantum field

We show an analogy between static quantum emitters coupled to a single mode of a quantum field and accelerated Unruh-DeWitt detectors. We envision a way to simulate a variety of relativistic quantum field settings beyond the reach of current computational power, such as high number of qubits coupled to a quantum field following arbitrary non-inertial trajectories. Our scheme may be implemented with trapped ions and circuit QED set-ups.Comment: 5 pages, 2 figures, revtex 4-

Thermodynamics, transition dynamics, and texturing in polymer-dispersed liquid crystals with mesogens exhibiting a direct isotropic/smectic-A transition

Experimental and modeling/simulation studies of phase equilibrium and growth morphologies of novel polymer-dispersed liquid crystal (PDLC) mixtures of PS (polystyrene) and liquid crystals that exhibit a direct isotropic/smectic-A (lamellar) mesophase transition were performed for PS/10CB (decyl- cyanobiphenyl) and PS/12CB (dodecyl-cyanobiphenyl). Partial phase diagrams were determined using polarized optical microscopy (POM) and differential scanning calorimetry (DSC) for different compositions of both materials, determining both phase separation (liquid/liquid demixing) and phase ordering (isotropic/smectic-A transition) temperatures. The Flory-Huggins theory of isotropic mixing and Maier-Saupe-McMillan theory for smectic-A liquid crystalline ordering were used to computationally determine phase diagrams for both systems, showing good agreement with the experimental results. In addition to thermodynamic observations, growth morphology relations were found depending on phase transition sequence, quench rate, and material composition. Three stages of liquid crystal-rich domain growth morphology were observed: spherical macroscale domain growth ("stage I"), highly anisotropic domain growth ("stage II"), and sub-micron spheroid domain growth ("stage III"). Nano-scale structure of spheroidal and spherocylindrical morphologies were then determined via two-dimensional simulation of a high-order Landau-de Gennes model. Morphologies observed during stage II growth are typical of di- rect isotropic/smectic-A phase transitions, such as highly anisotropic "batonnets" and filaments. These morphologies, which are found to be persistent in direct isotropic/smectic-A PDLCs, could provide new functionality and applications for these functional materials.Comment: First Revision, 21 pages, 11 figures, submitted to Macromolecules as an article 17JUL200